Pentaaqua(dimethylformamide)cobalt(II) sulfate dimethylformamide monosolvate
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منابع مشابه
Pentaaqua(dimethylformamide)cobalt(II) sulfate dimethylformamide monosolvate
The title compound, [Co(C3H7NO)(H2O)5]SO4·C3H7NO, contains five aqua ligands, a Co(II) atom, a sulfate ion and both a coordinating and a non-coordinating di-methyl-formamide (DMF) mol-ecule. The DMF solvent mol-ecule lies between the complex units, which are located along the b axis. The sulfate ion is for charge balance. The Co(II) atom has distorted octa-hedral coordination geometry, being li...
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In the title compound, C(6)H(16)N(2)O(2+)·SO(4) (2-)·CH(3)OH, the morpholinium ring of the dication adopts a chair conformation. The crystal structure is stabilized by an extensive three-dimensional network of inter-molecular O-H⋯O, N-H⋯O, O-H⋯S and N-H⋯S hydrogen bonds.
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Facial flushing and other symptoms were reported by 19 of a group of 102 men who worked with dimethylformamide (DMF). Twenty-six of the 34 episodes occurred after the workers had consumed alcoholic drinks. The metabolite N-methylformamide (MF) was detected in the urine on 45 occasions, the highest recorded concentration being 77 microliter/litre. The highest recorded concentration of DMF in air...
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The boiling point is 1530 C., and it is miscible with water and some organic solvents. On boiling with water or alkali it hydrolyzes to formic acid and dimethylamine. It is more stable than formamide and can be distilled. For the present work freshly distilled dimethylformamide was used and all aqueous solutions were freshly prepared. Dimethylformamide in the atmosphere may be trapped by passin...
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The key steps in oligosaccharide synthesis are protectinggroup manipulation and stereoselective glycosylation. Various strategies have emerged to expedite glycosylation, and some of these strategies have been elaborated for automated solid-phase synthesis and one-pot cascade glycosylation. Most glycosylation strategies rely on traditional methods for stereochemical control over glycosidic-bond ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813012841